Co(h2o)6 3+ high spin or low spin
Co(h2o)6 3+ high spin or low spin
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Water is a weak field ligand (high spin) so the electron configuration is t 2g 3 e g 2 with lfse = 0. Cyanide is a strong field ligand (low spin) so the electron configuration is t 2g 5 with lfse = –20dq + 2p. [fe(cn) 6] 3– has the larger lfse (more stabilization). (d) [fe(cn) 6] 3– or [ru(cn) 6] 3–. Ni 2+: [ar]3d 8 cn is a strong field ligand –> low spin. Ti(h 2 o) 6 2+ (octahedral) ti 2+: [ar]3d 2 h 2 o is a weak field ligand –> high spin. Nicl 4 2- (tetrahedra1) ni 2+: [ar]3d 8 cl is a weak field ligand –> high spin. Cof 6 3-(high-spin complex) co 3+: [ar]3d 6 f is a weak field ligand –> high spin. Different ligands are associated with either high or low spin — a "strong field" ligand results in a large ∆o and a low spin configuration, while a "weak field" ligand results in a small ∆o and a high spin configuration. For more details, see the crystal field theory (cft) page. Question: how many unpaired electrons do you expect for [co(cn)6]3- ? is this a high-spin or low-spin complex ion? Question 18 20 pts consider two octahedral complexes of co3+: [co (cn). 13- and (co (h2o). ]3+ (20 points) (a). Use the following diagrams to indicate the possible orbital diagrams for [co (cn)6] and [co (h20). ]3+ (assume octahedral geometries for both). Do you expect the \([cof_6]^{3-}\) complex ion to be high or low spin? solution. What do we know? the complex has an octahedral shape; f-is a weak-field ligand; the d electron configuration for co is d 6; the splitting energy is small; therefore, the complex is high spin Ghosts Blank spaces found on slot machines, co(h2o)6 3+ high spin or low spin.
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Co(h2o)6 3+ high spin or low spin, best slots in biloxi
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